Electron microscopy and ab-initio calculations

Scanning electron microscopy and EPMA

Scanning electron microscopy (SEM) readily provides images of the surface morphology of investigated materials down to nm level.  Combined with spectroscopy techniques it additionally enables determination of the chemical composition of investigated materials in bulk and layered structures with analytical spatial resolution in micrometre range. The group has vast knowledge in SEM (SE, BSE, ADF) imaging as well as in semi-quantitative and quantitative EDS and WDS analysis using large set of standard/reference materials. The crystallographic studies of materials, i.e. texture determination, are obtained by the EBSD. E-lithography is also available on the FEG-SEM.

Secondary electrons HR SEM images of TiO2 nanoparticles and BSE and SE images of varistor ceramics.

 

EDS X-ray mapping, EDS single spectrum and quantitative WDS elemental profile.

 

Example of EBSD texture determination in polycrystalline ceramic material.
Contact:
Prof. Miran Čeh Head of the Centre for Electron Microscopy and Microanalysis, senior scientist, scientific advisor

+386 1 4773 341
+386 41 743 265
miran.ceh@ijs.siRESEARCHGATESICRIS
Field of research:
  • Functional ceramics with perovskite structure, thermoelectrics
  • 1-D oxide nanostructures
  • Solar cells
  • Photocatalytic (micro)reactors
  • Electron microscopy (SEM, EPMA, STEM/TEM, AEM, HR HAADF-STEM)

Personal page

Dr. Zoran Samardžija Senior scientist

+386 1 4773 847
zoran.samardzija@ijs.siRESEARCHGATESICRIS
Field of research:
  • A specialist for scanning electron microscopy (SEM) and electron-probe microanalysis (EDXS, WDXS)

Transmission electron microscopy

Transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM) techniques combined with spectroscopic methods (EDS, EELS) readily provide structural and chemical information of materials on nano and atomic scale. While electron diffraction techniques (SAD, CBED, precession technique) provide information on the structure of crystalline nanostructures (grains, precipitates, etc.), HRTEM imaging with image simulations yield structural models of interfaces and planar faults. STEM ADF, HAADF and ABF provide atom resolved chemical information based on the measured intensities of individual atom columns. Chemical information can be further obtained by EDS and EELS (atom resolved mappings, line profiles, 2D valence state distribution, plasmonic studies, etc.). The research groups has access to the state-of-art (S)TEM equipment, i.e. Cs corrected STEM, and a long term collaboration with the partners within the ESTEEM and ESTEEM2 consortium.

FIB preparation of a thin lamella for (S)TEM investigation.

HR HAADF STEM image of a In-rich planar fault in ZnO grain.

HRTEM image of twinned taffeite structure.

EDS atom resolved X-ray mapping of SrTiO3.

 

Contact:
Prof. Miran Čeh Head of the Centre for Electron Microscopy and Microanalysis, senior scientist, scientific advisor

+386 1 4773 341
+386 41 743 265
miran.ceh@ijs.siRESEARCHGATESICRIS
Field of research:
  • Functional ceramics with perovskite structure, thermoelectrics
  • 1-D oxide nanostructures
  • Solar cells
  • Photocatalytic (micro)reactors
  • Electron microscopy (SEM, EPMA, STEM/TEM, AEM, HR HAADF-STEM)

Personal page

Prof. Aleksander Rečnik Senior scientist

+386 1 4773 815
aleksander.recnik@ijs.siRESEARCHGATESICRIS
Field of research:
  • Atomic-level studies of polytypic phase transitions, twinning, epitaxy, nucleation of planar faults; atomic structure & chemistry of twin boundaries, inversion boundaries, antiphase boundaries, low-angle tilt grain boundaries; special grain boundaries and their relation to exaggerated and anisotropic crystal growth; microstructure development.

In situ electron microscopy

Significant advances in the development of novel functional nanomaterials can be achieved by using suitable microscopy methods that allow in situ dynamic investigations of nanomaterials in their native environments at the highest spatial resolution. That includes nanoscale dynamic studies of nucleation and growth of nanomaterials as a function of temperature (in-situ heating/cooling). To bridge the gap between conventional (high-vacuum) and in-situ liquid TEM we have recently implemented an interdisciplinary research platform for dynamic TEM studies in liquid environments that are overcoming the static limitations of conventional analysis techniques. This ground-braking approach opens wide range of possibilities in high-resolution in situ dynamic studies where case-by-case specialized experiments can be performed by proper redesign of liquid chambers, allowing to perform direct nucleation and growth studies of nanoparticles either from solutions or during the electrodeposition, at the nanoscale and in real time.

The nucleation of gold nanoparticles from acqueous solution.

 

 

 

Contact:
Prof. Sašo Šturm Senior scientist

+386 1 4773 418
saso.sturm@ijs.siRESEARCHGATESICRIS
Field of research:
  • Material processing:
    • Solid state synthesis of functional ceramics
    • Hydrothermal synthesis of nanomaterials
  • Advanced TEM characterization and method developments:
    • Structural and chemical characterization of materials and correlation to properties at high spatial resolution
    • Quantitative atomic-scale studies of crystal structure, chemistry and bonding of interfaces and nanostructures
    • Quantitative atomic resolution HRTEM and HAADF/ABF/BF STEM image analysis
    • Quantitative EELS analysis
  • In situ transmission electron microscopy:
    • In situ heating and cooling TEM experiments
    • In situ studies of structural phase transitions

Modelling of technologically important properties

Design of novel materials with well-defined target properties is no more based just on a trial-and-error approach but it is ever more oriented towards understanding the background mechanisms responsible for the observed behavior. Fundamentally all processes in materials originate from interactions between the electrons forming the matter, which can be explained in terms of quantum mechanics. Therefore the complete understanding of the relation between the electronic structure and the results of various experiments, from the X-ray scattering, electron-microscope imaging, the measurements of mechanic, thermal, electric, magnetic and other properties, is of great importance. At the Department for Nanostructured materials of Jožef Stefan Institute we combine experimental activities with ab-initio modelling within the framework of the density-functional theory. This is the state-of-the-art method to simulate the ground-state crystal structures, magnetic ordering, elasticity, response to various external fields etc. without adjusting any phenomenological parameters,, just by applying the electron configuration of the included atoms and starting atomic positions.

The results of such calculations can serve either as a prediction or as an interpretation of experimental findings.

Contact:
Asst. Prof. Matej Komelj Scientist

+386 1 4773 308
matej.komelj@ijs.siRESEARCHGATESICRIS
Field of research:
  • Ab-initio electronic structure calculations, based on the density functional theory, focused on magnetic properties of solids, namely hyperfine parameters, nonlinear magnetoelastic effects, X-ray magnetic dichroism (XMCD) spectra…